Direct Measurement of Single CdSe Nanowire Extinction Polarization Anisotropies. Journal Article uri icon

Overview

abstract

  • The origin of sizable absorption polarization anisotropies (ρabs) in one-dimensional (1D) semiconductor nanowires (NWs) has been debated. Invoked explanations employ either classical or quantum mechanical origins, where the classical approach suggests dielectric constant mismatches between the NW and its surrounding environment as the predominant source of observed polarization sensitivities. At the same time, the confinement-influenced mixing of states suggests a sizable contribution from polarization-sensitive transition selection rules. Sufficient evidence exists in the literature to support either claim. However, in all cases, these observations stem from excitation polarization anisotropy (ρexc) studies, which only indirectly measure ρabs. In this manuscript, we directly measure the band edge extinction polarization anisotropies (ρext) of individual CdSe NWs using single NW extinction spectroscopy. Observed polarization anisotropies possess distinct spectral features and wavelength dependencies that correlate well with theoretical transition selection rules derived from a six-band k·p theory used to model the electronic structure of CdSe NWs.

publication date

  • August 16, 2012

Date in CU Experts

  • September 2, 2015 5:00 AM

Full Author List

  • McDonald MP; Vietmeyer F; Kuno M

author count

  • 3

Other Profiles

International Standard Serial Number (ISSN)

  • 1948-7185

Additional Document Info

start page

  • 2215

end page

  • 2220

volume

  • 3

issue

  • 16