A Highly Stable Zeotype Mesoporous Zirconium Metal–Organic Framework with Ultralarge Pores Journal Article uri icon



  • AbstractThrough topological rationalization, a zeotype mesoporous Zr‐containing metal–organic framework (MOF), namely PCN‐777, has been designed and synthesized. PCN‐777 exhibits the largest cage size of 3.8 nm and the highest pore volume of 2.8 cm3 g−1 among reported Zr‐MOFs. Moreover, PCN‐777 shows excellent stability in aqueous environments, which makes it an ideal candidate as a support to incorporate different functional moieties. Through facile internal surface modification, the interaction between PCN‐777 and different guests can be varied to realize efficient immobilization.

publication date

  • January 2, 2015

has restriction

  • bronze

Date in CU Experts

  • August 14, 2019 11:49 AM

Full Author List

  • Feng D; Wang K; Su J; Liu T; Park J; Wei Z; Bosch M; Yakovenko A; Zou X; Zhou H

author count

  • 10

Other Profiles

International Standard Serial Number (ISSN)

  • 0044-8249

Electronic International Standard Serial Number (EISSN)

  • 1521-3757

Additional Document Info

start page

  • 151

end page

  • 156


  • 127


  • 1