Small-scale variations within the low-level outflow and inflow of an MCS can either support or deter the upscale growth and maintenance of the MCS. However, these small-scale variations, in particular in the thermodynamics (temperature and humidity), remain poorly understood, due to a lack of detailed measurements. The compact Raman lidar (CRL) deployed on the University of Wyoming King Air aircraft directly sampled temperature and water vapor profiles at unprecedented vertical and along-track resolutions along the southern margin of a series of mature nocturnal MCSs traveling along a frontal boundary on 1 July 2015 during the Plains Elevated Convection at Night (PECAN) campaign. Here, the capability of the airborne CRL to document interactions between the MCS inflow and outflow currents is illustrated. The CRL reveals the well-defined boundary of a cooler current. This is interpreted as the frontal boundary sharpened by convectively induced cold pools, in particular by the outflow boundary of the downstream MCS. In one CRL transect, the frontal/outflow boundary appeared as a distinct two-layer structure of moisture and aerosols formed by moist stable boundary layer air advected above the boundary. The second transect, one hour later, reveals a single sloping boundary. In both cases, the lofting of the moist stably stratified air over the boundary favors MCS maintenance, through enhanced elevated CAPE and reduced CIN. The CRL data are sufficiently resolved to reveal Kelvin–Helmholtz (KH) billows and the vertical structure of the outflow boundary, which in this case behaved as a density current rather than an undular bore.