Macromolecules Journal

Research

keywords

• 03 Chemical Sciences, 09 Engineering

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publication venue for

• Effects of Thiol Substitution on the Kinetics and Efficiency of Thiol-Michael Reactions and Polymerizations 2021
• Enamine Organocatalysts for the Thiol-Michael Addition Reaction and Cross-Linking Polymerizations 2021
• Effects of Network Structures on the Tensile Toughness of Copper-Catalyzed Azide–Alkyne Cycloaddition (CuAAC)-Based Photopolymers 2021
• Spatially Controlled Permeability and Stiffness in Photopatterned Two-Stage Reactive Polymer Films for Enhanced CO2 Barrier and Mechanical Toughness 2021
• Computational and Experimental Evaluation of Peroxide Oxidants for Amine-Peroxide Redox Polymerization 2020
• Solvent Effects and Side Reactions in Organocatalyzed Atom Transfer Radical Polymerization for Enabling the Controlled Polymerization of Acrylates Catalyzed by Diaryl Dihydrophenazines 2020
• Phototriggered Base Amplification for Thiol-Michael Addition Reactions in Cross-linked Photopolymerizations with Efficient Dark Cure 2020
• Effects of 1 degrees, 2 degrees, and 3 degrees Thiols on Thiol-Ene Reactions: Polymerization Kinetics and Mechanical Behavior 2020
• Evaluation of Aromatic Thiols as Photoinitiators 2020
• High-Efficiency Radical Photopolymerization Enhanced by Autonomous Dark Cure 2020
• Polyelectrolyte Surface Diffusion in a Nanoslit Geometry 2020
• Bioerodible Hydrogels Based on Photopolymerized Poly(ethylene glycol)-co-poly(alpha-hydroxy acid) Diacrylate Macromers 2020
• Deformation and Elastic Recovery of Acrylate-Based Liquid Crystalline Elastomers 2019
• Thermal Metamorphosis in (Meth)acrylate Photopolymers: Stress Relaxation, Reshaping, and Second-Stage Reaction 2019
• Tuning Metastability of Poly(3-hexyl thiophene) Solutions to Enable in Situ Atomic Force Microscopy Imaging of Surface Nucleation 2019
• Independent Control of Singlet Oxygen and Radical Generation via Irradiation of a Two-Color Photosensitive Molecule 2019
• Impact of the Pendant Group on the Chain Conformation and Bulk Properties of Norbornene Imide-Based Polymers 2019
• Effects of Randomly End-Linked Copolymer Network Parameters on the Formation of Disordered Cocontinuous Phases 2019
• Ring-Opening Polymerization of Allyl-Functionalized Lactams 2019
• Chemomechanics in the Moisture-Induced Malleability of Polyimine-Based Covalent Adaptable Networks 2018
• Statistical Damage Mechanics of Polymer Networks 2018
• Mechanistic Modeling of the Thiol-Michael Addition Polymerization Kinetics: Structural Effects of the Thiol and Vinyl Monomers 2018
• Reconfigurable LC Elastomers: Using a Thermally Programmable Monodomain To Access Two-Way Free-Standing Multiple Shape Memory Polymers 2018
• Microstructural Evolution of the Thin Films of a Donor-Acceptor Semiconducting Polymer Deposited by Meniscus-Guided Coating 2018
• Three Regimes of Polymer Surface Dynamics under Crowded Conditions 2018
• Dynamic Changes in Material Properties and Degradation of Poly(ethylene glycol)-Hydrazone Gels as a Function of pH 2017
• Wavelength-Selective Sequential Polymer Network Formation Controlled with a Two-Color Responsive Initiation System 2017
• Anisotropic and Interconnected Nanoporous Materials from Randomly End-Linked Copolymer Networks 2017
• Remoldable Thiol-Ene Vitrimers for Photopatterning and Nanoimprint Lithography 2016
• Mechanistic Kinetic Modeling of Thiol-Michael Addition Photopolymerizations via Photocaged "Superbase" Generators: An Analytical Approach 2016
• Mechanics of a Dual Cross-Link Gel with Dynamic Bonds: Steady State Kinetics and Large Deformation Effects 2016
• Reconfiguring Nanocomposite Liquid Crystal Polymer Films with Visible Light 2016
• Thermomechanical Formation-Structure-Property Relationships in Photopolymerized Copper-Catalyzed Azide-Alkyne (CuAAC) Networks 2016
• Monodispersity/Narrow Polydispersity Cross-Linked Microparticles Prepared by Step-Growth Thiol-Michael Addition Dispersion Polymerizations 2015
• Functional Sulfobetaine Polymers: Synthesis and Salt-Responsive Stabilization of Oil-in-Water Droplets 2015
• Coupled UV Vis/FT-NIR Spectroscopy for Kinetic Analysis of Multiple Reaction Steps in Polymerizations 2015
• Dynamic Molecular Behavior on Thermoresponsive Polymer Brushes 2015
• Twists and Turns in Glassy, Liquid Crystalline Polymer Networks 2015
• Time Dependent Behavior of a Dual Cross-Link Self-Healing Gel: Theory and Experiments 2014
• Molecular Interactions and Ordering in Electrically Doped Polymers: Blends of PBTTT and F(4)TCNQ 2014
• Spatial and Temporal Control of Thiol-Michael Addition via Photocaged Superbase in Photopatterning and Two-Stage Polymer Networks Formation 2014
• Facile and Efficient Synthesis of Dendrimers and One-Pot Preparation of Dendritic-Linear Polymer Conjugates via a Single Chemistry: Utilization of Kinetically Selective Thiol-Michael Addition Reactions 2014
• Triple Shape Memory Materials Incorporating Two Distinct Polymer Networks Formed by Selective Thiol-Michael Addition Reactions 2014
• A Dual-Cure, Solid-State Photoresist Combining a Thermoreversible Diels-Alder Network and a Chain Growth Acrylate Network 2014
• High Performance Graded Rainbow Holograms via Two-Stage Sequential Orthogonal Thiol-Click Chemistry 2014
• Effect of Backbone Regioregularity on the Structure and Orientation of a Donor-Acceptor Semiconducting Copolymer 2014
• Controllable Reversible Addition-Fragmentation Termination Monomers for Advances in Photochemically Controlled Covalent Adaptable Networks 2014
• Characterization of Heterogeneous Polyacrylamide Hydrogels by Tracking of Single Quantum Dots 2014
• Impact of Backbone Rigidity on the Photomechanical Response of Glassy, Azobenzene-Functionalized Polyimides 2014
• Measurement of Viscoelastic Loss Tangent with Contact Resonance Modes of Atomic Force Microscopy 2013
• Cross-Linked Ultrathin Polyurea Films via Molecular Layer Deposition 2013
• Mechanical Properties and Degradation of Chain and Step-Polymerized Photodegradable Hydrogels 2013
• Effect of Cross-Link Density on Photoplasticity of Epoxide Networks Containing Allylic Dithioether Moieties 2012
• Highly Branched Polyisobutylene by Radical Polymerization under Li[CB11(CH3)(12)] Catalysis 2012
• A Simple Relationship Relating Linear Viscoelastic Properties and Chemical Structure in a Model Diels-Alder Polymer Network 2012
• Tailoring the Photomechanical Response of Glassy, Azobenzene-Functionalized Polyimides by Physical Aging 2012
• Photochemical Mechanism and Photothermal Considerations in the Mechanical Response of Monodomain, Azobenzene-Functionalized Liquid Crystal Polymer Networks 2012
• Poly(3-hexylthiophene) and [6,6]-Phenyl-C-61-butyric Acid Methyl Ester Mixing in Organic Solar Cells 2012
• Stress Reduction and T-g Enhancement in Ternary Thiol-Yne-Methacrylate Systems via Addition-Fragmentation Chain Transfer 2012
• Stress Relaxation via Addition-Fragmentation Chain Transfer in High T-g, High Conversion Methacrylate-Based Systems 2012
• Gelation of Copolymers with Pendent Benzophenone Photo-Cross-Linkers 2012
• Morphological Phase Behavior of Poly(RTIL)-Containing Diblock Copolymer Melts 2012
• A Quantitative Correlation between the Mobility and Crystallinity of Photo-Cross-Linkable P3HT 2012
• Instabilities of PS/PMMA Bilayer Patterns with a Corrugated Surface and Interface 2012
• Reaction Kinetics and Reduced Shrinkage Stress of Thiol-Yne-Methacrylate and Thiol-Yne-Acrylate Ternary Systems 2011
• Hybrid Organic/Inorganic Thiol-Ene-Based Photopolymerized Networks 2011
• Real-Time Observation of Poly(3-alkylthiophene) Crystallization and Correlation with Transient Optoelectronic Properties 2011
• Structure and Mechanism of Strength Enhancement in Interpenetrating Polymer Network Hydrogels 2011
• Drastic Control of Texture in a High Performance n-Type Polymeric Semiconductor and Implications for Charge Transport 2011
• Synthesis and Ordered Phase Separation of Imidazolium-Based Alkyl-Ionic Diblock Copolymers Made via ROMP 2011
• Induction Curing of Thiol-Acrylate and Thiol-Ene Composite Systems 2011
• Photomechanical Response of Glassy Azobenzene Polyimide Networks 2011
• Photodegradable, Photoadaptable Hydrogels via Radical-Mediated Disulfide Fragmentation Reaction 2011
• Radical Copolymerization of Isobutylene and Ethyl Acrylate with LiCB11Me12 Catalyst 2011
• Assembly of Poly(3-hexylthiophene)/CdSe Hybrid Nanowires by Cocrystallization 2011
• Highly Branched Polypropylene via Li+-Catalyzed Radical Polymerization 2011
• Relationship between Glass Transition Temperature and Polymerization Temperature for Cross-Linked Photopolymers 2011
• Stress Relaxation by Addition-Fragmentation Chain Transfer in Highly Cross-Linked Thiol-Yne Networks 2010
• Mechanism and Implementation of Oxygen Inhibition Suppression in Photopolymerizations by Competitive Photoactivation of a Singlet Oxygen Sensitizer 2010
• Relationship between the Photomechanical Response and the Thermomechanical Properties of Azobenzene Liquid Crystalline Polymer Networks 2010
• Stability and Surface Topography Evolution in Nanoimprinted Polymer Patterns under a Thermal Gradient 2010
• Solvent-Driven Evolution of Block Copolymer Morphology under 3D Confinement 2010
• Morphology of Photopolymerized End-Linked Poly(ethylene glycol) Hydrogels by Small-Angle X-ray Scattering 2010
• From Dendrimers to Dendronized Polymers and Forests: Scaling Theory and its Limitations 2010
• Synthesis, Thiol-Yne "Click" Photopolymerization, and Physical Properties of Networks Derived from Novel Multifunctional Alkynes 2010
• Reaction Rates and Mechanisms for Radical, Photoinitated Addition of Thiols to Alkynes, and Implications for Thiol-Yne Photopolymerizations and Click Reactions 2010
• Interfacial Segregation in Polymer/Fullerene Blend Films for Photovoltaic Devices 2010
• Tailored Assemblies of Block Copolymers in Solution: It Is All about the Process 2010
• Synthesis of End-Functionalized Polystyrene by Direct Nucleophilic Addition of Polystyryllithium to Bipyridine or Terpyridine 2010
• Covalent Adaptable Networks (CANS): A Unique Paradigm in Cross-Linked Polymers 2010
• Clipped Random Wave Morphologies and the Analysis of the SAXS of an Ionomer Formed by Copolymerization of Tetrafluoroethylene and CF2=CFO(CF2)(4)SO3H 2009
• Dielectric Spectroscopy Investigation of Relaxation in C-60-Polyisoprene Nanocomposites 2009
• Rapid Solid-State Photopolymerization of Cyclic Acetal-Containing Acrylates 2009
• Stress Relaxation via Addition-Fragmentation Chain Transfer in a Thiol-ene Photopolymerization 2009
• Influence of Interfacial Layer Between Nanoparticles and Polymeric Matrix on Viscoelastic Properties of Hydrogel Nanocomposites 2009
• Thiol-Yne Photopolymerizations: Novel Mechanism, Kinetics, and Step-Growth Formation of Highly Cross-Linked Networks 2009
• Reactivity of Monovinyl (Meth)acrylates Containing Cyclic Carbonates 2008
• Rheological and Chemical Analysis of Reverse Gelation in a Covalently Cross-Linked Diels-Alder Polymer Network 2008
• Wormlike Micelles with Microphase-Separated Cores from Blends of Amphiphilic AB and Hydrophobic BC Diblock Copolymers 2008
• Synthesis, Characterization and Cleavage of Surface-Bound Linear Polymers Formed Using Thiol-Ene Photopolymerizations 2008
• Mixed mode thiol-acrylate photopolymerizations for the synthesis of PEG-peptide hydrogels 2008
• Molecular basis of mesophase ordering in a thiophene-based copolymer 2008
• Nonclassical dependence of polymerization rate on initiation rate observed in thiol-ene photopolymerizations 2008
• Crystalline structure in thin films of DEH-PPV homopolymer and PPV-b-PI rod-coil block copolymers 2008
• Kinetic modeling of a comonomer photopolymerization system using high-throughput conversion data 2008
• Critical role of side-chain attachment density on the order and device performance of polythiophenes 2007
• Design, development, and evaluation of monovinyl acrylates characterized by secondary functionalities as reactive diluents to diacrylates 2007
• Kinetic and mechanistic studies of photopolymerizations of acrylates in the presence of iniferters 2007
• Surface modification using thiol-acrylate conjugate addition reactions 2007
• Thiol-allyl ether-methacrylate ternary systems. Evolution mechanism of polymerization-induced shrinkage stress and mechanical properties 2007
• Thiol-allyl ether-methacrylate ternary systems. Polymerization mechanism 2007
• Monomer functionality effects in the formation of thiol-ene holographic polymer dispersed liquid crystals 2007
• Polymerization kinetics and monomer functionality effects in thiol-ene polymer dispersed liquid crystals 2007
• Deconvoluting the impact of intermolecular and intramolecular interactions on the polymerization kinetics of ultrarapid mono(meth)acrylates 2007
• Entropic elasticity of DNA with a permanent kink 2006
• Network development in mixed step-chain growth thiol-vinyl photopolymerizations 2006
• Gel permeation chromatography characterization of the chain length distributions in thiol-acrylate photopolymer networks 2006
• Ultrathin patterned polymer films on surfaces using thiol-ene polymerizations 2006
• Chemical modification of fluorinated polyimides: New thermally curing hybrid polymers with POSS 2006
• Thiol-vinyl mechanisms. 1. Termination and propagation kinetics in thiol-ene photopolymerizations 2006
• Thiol-vinyl mechanisms. 2. Kinetic modeling of ternary thiol-vinyl photopolymerizations 2006
• Breakdown of time-temperature superposition principle and universality of chain dynamics in polymers 2006
• Impact of oxygen on photopolymerization kinetics and polymer structure 2006
• Thiol-ene photopolymer grafts on functionalized glass and silicon surfaces 2006
• Evaluation of a potential ionic contribution to the polymerization of highly reactive (meth)acrylate monomers 2005
• Template cross-linking effects on morphologies of swellable block copolymer and mesostructured silica thin films 2005
• Propagation and termination kinetics of cross-linking photopolymerizations studied using electron paramagnetic resonance spectroscopy in conjunction with near IR spectroscopy 2005
• An investigation of chain length dependent termination and reaction diffusion controlled termination during the free radical photopolymerization of multivinyl monomers 2005
• A modeling investigation of chain length dependent termination during multivinyl free radical chain photopolymerizations: Accounting for the gel 2005
• Molecular weight development during thiol-ene photopolymerizations 2005
• Dependence of regioregular poly(3-hexylthiophene) film morphology and field-effect mobility on molecular weight 2005
• Effect of aliphatic spacer substitution on the reactivity of phenyl carbamate acrylate monomers 2005
• Investigation of molecular transport and distributions in poly(ethylene glycol) hydrogels with confocal laser scanning microscopy 2005
• Influence of molecular weight on fast dynamics and fragility of polymers 2004
• Observation of chain dynamics in depolarized light scattering spectra of polymers 2004
• Synthesis and characterization of photopolymerized multifunctional hydrogels: Water-soluble poly(vinyl alcohol) and chondroitin sulfate macromers for chondrocyte encapsulation 2004
• Effect of aryl substituents on the reactivity of phenyl carbamate acrylate monomers 2004
• Synthesis of Poly(2,5-thienyleneethynylene)s by Alkyne Metathesis 2004
• Experimental characterization of structural features during radical chain homopolymerization of multifunctional monomers prior to macroscopic gelation 2004
• Novel monovinyl methacrylic monomers containing secondary functionality for ultrarapid polymerization: Steady-state evaluation 2004
• When does a molecule become a polymer? 2004
• Thiol-ene photopolymerization mechanism and rate limiting step changes for various vinyl functional group chemistries 2003
• Modeling thermal and optical effects on photopolymerization systems 2003
• A methacrylated photoiniferter as a chemical basis for microlithography: Micropatterning based on photografting polymerization 2003
• FTIR and ESR spectroscopic studies of the photopolymerization of vinyl ester resins 2003
• Mechanism and modeling of a thiol-ene photopolymerization 2003
• Ordering and melting of block copolymer spherical domains in 2 and 3 dimensions 2003
• Glucose-Sensitive Aggregates Formed by Poly(ethylene oxide)-block-poly(2-glucosyl- oxyethyl acrylate) with Concanavalin A in Dilute Aqueous Medium 2003
• Coupling chain length dependent and reaction diffusion controlled termination in the free radical polymerization of multivinyl (meth)acrylates 2002
• Effect of primary cyclization on free radical polymerization kinetics: Modeling approach 2002
• Photopolymerizations of thiol-ene polymers without photoinitiators 2002
• Two-dimensional (2D) ATR-FTIR spectroscopic study on water diffusion in cured epoxy resins 2002
• Compressed antisolvent precipitation and photopolymerization to form highly cross-linked polymer particles 2002
• Surface-initiated photopolymerization of poly(ethylene glycol) methyl ether methacrylate on a diethyldithiocarbamate-mediated polymer substrate 2002
• Exploiting the heterogeneity of cross-linked photopolymers to create High-T-g polymers from polymerizations performed at ambient conditions 2001
• Using changes in initiation and chain transfer rates to probe the kinetics of cross-linking photopolymerizations: Effects of chain length dependent termination 2001
• Monomer functionality and polymer network formation 2001
• Predicting controlled-release behavior of degradable PLA-b-PEG-b-PLA hydrogels 2001
• Cross-linkable liquid crystal monomers containing hydrocarbon 1,3-diene tail systems 2000
• Release behavior of high molecular weight solutes from poly(ethylene glycol)-based degradable networks 2000
• Regenerated spider silk: Processing, properties, and structure 2000
• A novel sequential photoinduced living graft polymerization 2000
• Kinetics of primary cyclization reactions in cross-linked polymers: An analytical and numerical approach to heterogeneity in network formation 1999
• Modeling primary radical termination and its effects on autoacceleration in photopolymerization kinetics 1999
• Effect of polymerization temperature and cross-linker concentration on reaction diffusion controlled termination 1999
• Dynamics and shear orientation behavior of a main-chain thermotropic liquid crystalline polymer 1999
• Effects of composition and reactivity on the reaction kinetics of dimethacrylate dimethacrylate copolymerizations 1999
• Excluded volume effects in polymer solutions. 1. Dilute solution properties of linear chains in good and Theta solvents 1999
• Excluded-volume effects in polymer solutions. 2. Comparison of experimental results with numerical simulation data 1999
• Polymerization kinetics of pseudocrown ether network formation for facilitated transport membranes 1999
• Role of crystallinity in retention of polymer particle morphology in the presence of compressed carbon dioxide 1999
• MALDI-TOF characterization of highly cross-linked, degradable polymer networks 1999
• Synthesis and Characterization of Poly(2,5-bis(N-methyl-N-hexylamino)phenylene vinylene), a Conjugated Polymer for Light-Emitting Diodes 1998
• Synthesis and polymerization of a chiral liquid crystal diacrylate exhibiting smectic A* and C* phases 1998
• Reaction behavior of biodegradable, photo-cross-linkable polyanhydrides 1998
• Structural evolution of dimethacrylate networks studied by dielectric spectroscopy 1998
• Kinetic analysis of polymerization rate acceleration during the formation of polymer/smectic liquid crystal composites 1997
• Polymerization behavior and kinetics during the formation of polymer-stabilized ferroelectric liquid crystals 1997
• Kinetic and mechanistic studies of iniferter photopolymerizations 1996
• Gas sorption in polyaniline .1. Emeraldine base 1996
• Dynamical scaling of DNA diffusion coefficients 1996
• REAL-TIME INFRARED CHARACTERIZATION OF REACTION-DIFFUSION DURING MULTIFUNCTIONAL MONOMER POLYMERIZATIONS 1995
• REACTION-KINETICS AND VOLUME RELAXATION DURING POLYMERIZATIONS OF MULTIETHYLENE GLYCOL DIMETHACRYLATES 1995
• A PHOTOCHROMIC TECHNIQUE TO STUDY POLYMER NETWORK VOLUME DISTRIBUTIONS AND MICROSTRUCTURE DURING PHOTOPOLYMERIZATIONS 1994
• KINETIC EVIDENCE OF REACTION-DIFFUSION DURING THE POLYMERIZATION OF MULTI(METH)ACRYLATE MONOMERS 1994
• GRAZING-INCIDENCE X-RAY-SCATTERING STUDIES OF THIN-FILMS OF AN AROMATIC POLYIMIDE 1993
• SYNCHROTRON-GENERATED TIME-RESOLVED FLUORESCENCE ANISOTROPY STUDIES OF THE SEGMENTAL RELAXATION OF POLY(ACRYLIC ACID) AND POLY(METHACRYLIC ACID) IN DILUTE METHANOLIC SOLUTIONS 1992
• COUPLING OF KINETICS AND VOLUME RELAXATION DURING POLYMERIZATIONS OF MULTIACRYLATES AND MULTIMETHACRYLATES 1991
• LASER DESORPTION MASS-SPECTROMETRY OF POLYSILANES 1989
• TRANSIENT DECAY STUDIES OF PHOTOPHYSICAL PROCESSES IN AROMATIC POLYMERS .7. STUDIES OF THE MOLECULAR-WEIGHT DEPENDENCE OF INTRAMOLECULAR EXCIMER FORMATION IN POLYSTYRENE AND STYRENE BUTADIENE BLOCK CO-POLYMERS 1983